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With a standard reduction potential (E0) of −0.44 V, the Fe0 core can reductively dehalogenate chlorinated organic solvents and reduce mobile, high-oxidation-state metals and metalloids to less toxic, immobile forms.51,52 A key example is the reduction of hexavalent chromium:2CrO42− + 3Fe0 + 16H+ → 2Cr3+ + 3Fe2+ + 8H2OThe study by Zhang et al.,49 which integrated nZVI with biochar, highlights a common strategy to mitigate the rapid aggregation and surface passivation that plagues bare nZVI

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Yet, these derivatives require electron ionization (EI) which lacks sensitivity